| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5183948 | Polymer | 2011 | 5 Pages |
Abstract
A new reactive and functionalized polystyrene with a maleimide moiety at the one polymer end was synthesized with N-(4-(1-chloroethyl)pheyl)maleimide (CEPMI)/SnCl4/tetra-butylammonium chloride (TBAC) initiating system. The polymer obtained with the CEPMI/SnCl4/TBAC initiating system under the condition of [TBAC]/[SnCl4]Â =Â 1 was to be maleimide-type macromonomer with polystyrene having controlled molecular weight of polystyrene (VI). VI could be polymerized with anionic and radical initiators to give new type graft polymer (poly[N-(4-ethylphenyl)maleimide]-graft-polystyrene) with controlled chain length with respect to side chains.
Graphical abstractDownload full-size image
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Shigeo Kuroda, Tokio Hagiwara,