| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5184179 | Polymer | 2011 | 10 Pages |
Abstract
Poly (4-chloromethyl styrene)/TiO2 nanocomposite was synthesized by in situ free radical polymerizing of 4-chloromethyl styrene monomers in the presence of3-(trimethoxysilyl) propylmethacrylate (MPS) modified nano-TiO2. Thereafter, synthesized TEMPO-terminated poly (4-chloromethyl styrene)/TiO2 macroinitiator, initiates ''living'' free radical polymerization of 4-vinylpyridine monomers to yield the controlled graft copolymer [(PCMS-g-P4VP)/TiO2]
Keywords
DMFDibenzoyl peroxide2,2,6,6-Tetramethyl-1-piperidinyloxyNMRPAIBNPCMsP4VPTGADSCN,N-dimethylformamideTemThermogravimetric analysisglass transition temperatureTEMPOSpecific surface areaBETTransmission electron microscopyTiO2 nanoparticlesMPsCRPpoly (4-vinylpyridine)In situ polymerizationNitroxide-mediated radical polymerizationcontrolled/living radical polymerizationDifferential scanning calorimetry
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Mehdi Jaymand,