Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5185098 | Polymer | 2010 | 7 Pages |
Abstract
Copper-catalyzed alkyne-azide “click chemistry” is applied in the preparation of tadpole-shaped (“monochelic”) POSS-end functional hybrid polymers by combining with ATRP and RAFT polymerization. Alkyne-functionalized ATRP initiator and RAFT agent were respectively synthesized and applied in the preparation of alkyne-terminal poly(methyl methacrylate) and polystyrene. The tadpole-shaped POSS-containing hybrid polymers are easily obtained by the click reaction with an azido-functional POSS molecule. This presents a novel and effective method to prepare POSS-containing hybrid polymers.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Weian Zhang, Axel H.E. Müller,