| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5186553 | Polymer | 2006 | 4 Pages |
Abstract
A new photoinitiating system for free radical polymerization of methyl methacrylate (MMA) is reported. This system consists of benzodioxinone and hydrogen donors such as triethylamine (TEA), N,N-dimethyl ethanol amine (DMEA) and tetrahydrofuran (THF). A feasible mechanism involves photoinduced formation of benzophenone from benzodioxinone and subsequent hydrogen abstraction of photoexcited benzophenone from hydrogen donors to yield radicals capable of initiating polymerization of MMA.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Mehmet Atilla Tasdelen, Volkan Kumbaraci, Naciye Talinli, Yusuf Yagci,