Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
51871 | Catalysis Communications | 2008 | 4 Pages |
Abstract
Au–Pd/Al2O3 catalyst was prepared by modified impregnation method. It was found that the catalyst calcined in air at 473 K showed higher CO oxidation activity in comparison with the catalysts treated at other temperature. Nitrogen adsorption, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and X-ray absorption near edge structure spectroscopy (XANES) techniques were employed to study the relationship between the surface/bulk structures of these catalysts and their catalytic performance. The results indicated the higher activity was attributed to the smaller pore volume and co-existence of PdO and Au0 in their surface. The formation of AuxPdy alloy was unfavorable for the catalytic reaction.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Zhanghuai Suo, Chunyan Ma, Mingshan Jin, Tao He, Lidun An,