Article ID Journal Published Year Pages File Type
5187757 Polymer 2007 8 Pages PDF
Abstract

Two new fluorescent second generation poly(propyleneimine) dendrimers, peripherally modified with 1,8-naphthalimide, have been synthesized for the first time and characterized. The photophysical characteristics of the new dendrimers have been studied in organic solvents of different polarity. The effect of the chemical nature of the 1,8-naphthalimide C-4 substituent on the photophysical properties of new dendrimers is discussed. The complexes formed between the dendrimers and the metal cations in solution have been studied, with regard to potential applications as fluorescent sensors for metal ion contamination. The results show that the C-4 substituent determines both the response to the presence of metal cations and the selectivity of the sensors.

Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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