Article ID Journal Published Year Pages File Type
5188414 Polymer 2006 4 Pages PDF
Abstract
The enhanced crystallization of polycarbonate in the blend of liquid crystalline polymer/polycarbonate/(ethylene-methyl acrylate-glycidyl methacrylate) copolymer (LCP/PC/E-MA-GMA) was studied by wide angle X-ray diffraction (WAXD) and differential scanning calorimetry (DSC). The LCP/PC/E-MA-GMA 5/95/5 blends annealed at 200 °C, for 2, 4, 6, and 10 h, present an obvious crystalline structure corresponding to PC crystallization. The PC crystal obtained shows two melting temperature, Tm1 of about 214 °C and Tm2 of about 231 °C, with a total heat of fusion of 29 J/g (annealing time = 10 h). The preliminary results indicate that amorphous PC can be induced to crystallization by the synergistic action of LCP dispersed phase and reactive compatibilizer.
Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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