Article ID Journal Published Year Pages File Type
5188994 Polymer 2006 10 Pages PDF
Abstract
Poly(dimethylsiloxane) (PDMS) interpenetrating networks (IPNs) of two different molecular weight PDMS were prepared. Six series of IPNs were obtained by first tetra-functionally end-linking long vinyl-terminated PDMS (molar mass 23 × 103 or 21 × 103 g mol−1) neat or in a 50% solution with unreactive PDMS chains. These networks were then dried and swollen with short reactive telechelic PDMSs (molar mass 800, 2.3 × 103 or 5.7 × 103 g mol−1) that were subsequently end-linked. The mechanical, toughness and swelling properties of these IPNs were investigated. We found that the correlation between modulus (E) and equilibrium swelling (Q) in toluene of the PDMS IPNs obeys a scaling relation identical to that of a normal unimodal PDMS network. This result strongly suggests effective load transfer between the networks. The results of the elastic modulus and of the toughness of the networks represented by the energy required to rupture them were analyzed in terms of a recent model by Okumura [Europhys Lett 2004;67:470.]. Although the modulus results are in reasonable agreement with the equal-stress model of Okumura, the toughness results are not. In addition, our measured toughness decreases instead of increases with composition in an opposite trend to that predicted by the equal-strain model. An empirical model based on fracture mechanics gives a good representation of the toughness data.
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Physical Sciences and Engineering Chemistry Organic Chemistry
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