Article ID Journal Published Year Pages File Type
5189129 Polymer 2006 6 Pages PDF
Abstract
A novel cationic fluorene-containing water-soluble poly(p-phenyleneethynylene) (PPE) derivative, poly[(9,9-bis{6′-[(N,N-diethyl)-N-methylammonium]hexyl}-2,7-fluorenyleneethynylene)-alt-co-(2,5-bis{3′-[(N,N-diethyl)-N-methylammonium]-1′-oxapropyl}-1,4-phenylene)] tetraiodide (P1′), was synthesized through Sonogashira reaction and a post-polymerization treatment. P1′ emits bright blue fluorescence in H2O with a high photoluminescence quantum yield (Φpl=26%). Studies on the optical properties and quenching experiments with Fe(CN)64− in H2O and MeOH show that P1′ presents minor aggregation and high Stern-Volmer constant (Ksv=2.4×108 M−1) in aqueous solution. The remarkably reduced tendency towards aggregation, relative to previously reported water-soluble PPEs, made the optical properties of P1′ almost insensitive to the disturbance from the common ions (non-quencher) in the solution.
Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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