Article ID Journal Published Year Pages File Type
5189404 Polymer 2006 6 Pages PDF
Abstract
Wholly aromatic polyamides were synthesized from the amidation reaction between unsymmetrical diamine containing a pyridyl ether linkage and aromatic dicarboxylic acid chloride. The resulting polyamides containing pyridyl ether linkages showed high thermal stability (Td5=467 °C) and enhanced solubility in organic solvents compared with the analogous polyamides having phenyl ether linkages. Substitution of just a single atom in a repeating unit was effective to disrupt the strong inter-chain interaction of parent aramid polymers.
Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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