Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5189827 | Polymer | 2005 | 11 Pages |
Abstract
This work describes the synthesis and characterisation of two types of thiophene-containing poly(arylene-ethynylene)-alt-poly(arylene-vinylene)s (PAE-PAV) copolymers, whose repeating units (-Ph-CC-Th-CHCH-Ph-CHCH-)n, 5, and (-Th-CC-Ph-CC-Th-CHCH-Ph-CHCH-)n, 8a-c, consist, respectively, of a 1:2 and a 2:2 ratio of triple bond/double bond moieties. Comparison of their photophysical, electrochemical and photovoltaic properties has been carried out. Although similar electrochemical data (HOMO: â5.43 eV, LUMO: â¼â3.15 eV, Egec=2.28eV) as well as identical thin film absorption behaviour (λa=500 nm, Egopt=2.10eV) were obtained for both types of materials, significant differences in their thin film photoluminescence behaviour and photovoltaic properties were observed. While polymer 5 shows a fluorescence maximum at λe=568 nm (with a fluorescence quantum yield of Φf=7%), a total fluorescence quenching was observed in 8. Far better photovoltaic performance was obtained from solar cells (set up: ITO/PEDOT:PSS/active layer/LiF/Al; active layer consisting of 5 or 8b as donor and PCBM as acceptor in a 1:3 ratio by weight) designed from 5 than from 8b. Open circuit voltage, VOC, as high as 900 mV and power conversion efficiency, ηAM1.5, around 1.2% were obtained. This can be attributed to the 1:2 triple bond/double bond ratio as well as the grafting of shorter octyloxy and 2-ethylhexyloxy side chains in 5 and to its comparatively higher molecular-weight.
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Daniel Ayuk Mbi Egbe, Le Huong Nguyen, Benjamin Carbonnier, David Mühlbacher, Niyazi Serdar Sariciftci,