Article ID Journal Published Year Pages File Type
5189947 Polymer 2007 7 Pages PDF
Abstract
Aggregates of a polymethylene-block-poly(dimethyl siloxane)-block-polymethylene (PM-PDMS-PM) sample were prepared in toluene by cooling down a toluene solution of the sample slowly from 105 °C to room temperature. Atomic force microscopic (AFM) and electron microscopic (EM) studies revealed that the aggregates included triblock crystal plates with sizes of upto tens of micrometers and PM-PDMS-PM nanodiscs. Surprisingly and interestingly, we discovered that the topographic images of the nanodiscs obtained by tapping-mode AFM changed from nanodiscs at light tapping to strikingly beautiful nanodonuts at moderate tapping and then filled nanodonuts at heavy tapping. Justification for such observations is provided.
Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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