Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5191124 | Polymer | 2005 | 11 Pages |
Abstract
The influence of well-dispersed nano-clay filler on the morphology of thermotropic liquid crystalline polymer (TLCP) in nylon-6 matrix was investigated by melt extrusion process. The good dispersion of clay in the hybrid blends was confirmed by X-ray diffraction, transmission electron microscopy and rheological measurement. Morphological observation showed that the clay platelets had dramatic influences on the dispersion and deformation of TLCP phase. The TLCP droplets got smaller at the clay content â¤3 wt%, and deformed into fibrils at the clay content up to 5 and 7 wt%. The morphology evolution of TLCP in the hybrid blends, especially at 7 wt% of clay loading, was consistent well with the prediction based on the micro-rheology parameters such as the viscosity ratio of the dispersed phase to the matrix (ηd/ηm) and the ratio of capillary number to the critical capillary number (Ca/Cacrit). This enhanced fibrillation of TLCP droplets was attributed to the role of nano-clay particles as a compatibilizer to improve the interfacial adhesion and to suppress the interfacial slip between TLCP and nylon phases in the melt, so that the shear stress was effectively transferred to the dispersed TLCP phase.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Baoqing Zhang, Yanfen Ding, Peng Chen, Chenyang Liu, Jun Zhang, Jiasong He, Guo-Hua Hu,