| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5191884 | Polymer | 2005 | 8 Pages |
Abstract
This work reports the experimental isotherms describing the concentration of oxygen and nitrogen in poly(bisphenol A carbonate-co-4,4â²-(3,3,5-trimethylcyclohexylidene) diphenol carbonate) vs pressure, at 30 °C. The solubility coefficients are interpreted in terms of the Flory-Huggins theory, obtaining reasonable values for the enthalpic polymer-gas parameter. A new method is outlined to simulate the probabilities of inserting/removing a gas molecule in a host matrix already containing n molecules of gas. The simulated isotherms representing the pressure dependence of the concentration exhibit the same pattern as those experimentally obtained.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
M. Mar López-González, Enrique Saiz, Evaristo Riande,