| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5203583 | Polymer Degradation and Stability | 2011 | 6 Pages |
Abstract
The thermal reactions of polybutadiene (PB) at 260 °C in inert atmosphere were followed by 1H and 13C NMR spectroscopy. Within 24 h of heating, the change in the intensities of some peaks and the appearance of new peaks of NMR spectra permits to follow the reactions occurring in polybutadiene. The sample, after heating for 6 h, was then characterized by a two dimensional HSQC NMR spectrum, showing the appearance of CH3CH moiety, and the migration of double bond in polybutadiene. From these results the new mechanism of intra/intermolecular reactions was proposed.
Keywords
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Nguyen Q. Hung, C. Sanglar, M.F. Grenier-Loustalot, Pham V. Huong, Hoang N. Cuong,