Carboxymethylation of hemicelluloses isolated from sugarcane bagasse

Hemicelluloses isolated from sugarcane bagasse were converted to carboxymethyl hemicelluloses (CMH) by carboxymethylation using sodium monochloroacetate and sodium hydroxide in ethanol/water medium. The reaction was performed under various temperatures, times, times of alkaline activation, the ways of the addition of alkali, and the amounts of sodium hydroxide and sodium monochloroacetate. The product had the maximum degree of substitution (DS) of 0.56. The structure of the resulting polymers was characterized with Fourier transform infrared (FT-IR) and 13C nuclear magnetic resonance (NMR) spectroscopies. Destructive methods such as thermal analysis and non-destructive techniques such as gel permeation chromatography (GPC) were used to characterize the carboxymethyl hemicellulose preparations. It was found that a significant degradation of the polymers occurred during carboxymethylation. The thermal stability of carboxymethyl hemicelluloses was higher than that of the native hemicelluloses.