Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5207890 | Progress in Polymer Science | 2017 | 185 Pages |
Abstract
One of the most important applications of graphene-based materials is the formation of nanocomposite materials, where graphene in the bulk-polymer matrix transfers its properties onto the polymeric material. Control of the polymer/graphene interface by attached polymeric interlayers is essential to generate nanocomposites, thus avoiding the aggregation of graphene nanoparticles. Among all graphene materials graphene oxide (GO) and reduced graphene oxide (r-GO) can be prepared on large scales useful for mass production graphene/polymer composites. The direct use of graphene materials as both, the polymerization initiator or catalyst and additive not only diminishes the agglomeration of particles in composites but also reduces the process of composite production to one facile step, which in turn avoids further purification regarding to strong acid initiators and metal particles catalysts. Here, literature activities within the past â¼10 years using graphene-based materials either as initiator or catalyst in different polymerization reactions are reviewed.
Keywords
AFMPDIDSCDMFK2CO3Fe2O3FCCFeCl3TGACNTNaBH4CuOHRTEMTrGOTHFAASCu2OP4VPDCMPAACuCl2Cu(acac)2EtOHNHCDMAPCuSO4PAM4-dimethylaminopyridineICP-AESGPCFWHMMMAFAASDDSMAODCCAgNO3PDMApHEMAAIBNCuAACAzobisisobutyronitrileROMPAPTMSPoly(N,N-dimethylacrylamide)TiCl4SOCl2Palladium(II) acetateCp2ZrCl2K2PdCl4CuBrButyllithiumVO(acac)2PA6KMnO4HAuCl4BuLiN2H4(3-Aminopropyl)trimethoxysilaneCopper (II) acetylacetonatenuclear magnetic resonancePolyacrylamide(3-Aminopropyl)triethoxysilaneDMSOPANIN-heterocyclic carbeneN,N′-dicyclohexylcarbodiimideN,N-dimethylformamidePd(OAc)2UV–VisInitiatorIron(III) chlorideEthanolEDTAEthylenediaminetetraacetic acidChloroauric acidchloroplatinic acidEnergy-Dispersive X-ray SpectroscopyUltraviolet–visibleMicrowave irradiationAluminium oxideAl2O3Thermally reduced graphene oxideTemTitanium tetrachlorideTetrahydrofuranDinitrogen tetroxideThermogravimetric analysisthermosetNMREPRElectron paramagnetic resonanceTiO2Thionyl chlorideTitanium dioxideDichloromethaneDimethyl sulfoxideChemical vapor depositionCVDSiO2Silicon dioxidepolydispersity indexFTIRinductively coupled plasma atomic emission spectroscopyAtomic absorption spectroscopyflame atomic absorption spectroscopyX-ray photoelectron spectroscopyFourier transform infrared spectroscopyXPSICP-MSinductively coupled plasma mass spectrometryfull width at half maximumIonic liquidMethanolMethyl methacrylateSEMCopper(II) acetateCopper(II) chlorideCu(OH)2Cu(OAc)2MeOHFace centered cubicscanning electron microscopeHigh Resolution Transmission Electron MicroscopyTransmission electron microscopyatomic force microscopyNAHNanoparticlesCarbon nanotubessilver nitrateNO2Nitrogen dioxideHydrazineXRDX-ray diffractionPoly(4-vinylpyridine)Poly(methyl methacrylate)PMMApoly(hydroxyethyl methacrylate)Polyanilinepoly(acrylic acid)PolypropylenePolymerizationRing-opening metathesis polymerizationPolystyreneCatalystDifferential scanning calorimetryGel permeation chromatographyGraphene
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Ali Shaygan Nia, Wolfgang H. Binder,