| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5208175 | Progress in Polymer Science | 2014 | 37 Pages |
Abstract
In this review article, recent developments in multidimensional characterization of segmented copolymers are presented. Liquid chromatography (LC) is the most widely used and versatile polymer fractionation technique to address different aspects of copolymer heterogeneity. The potential and limitations of different modes of liquid chromatography of polymers (size exclusion chromatography, different modes of interaction chromatography) and spectroscopic techniques (FTIR, NMR, and MALDI-TOF-MS) are elaborated. Possible method combinations including comprehensive two-dimensional LC and the hyphenation of various modes of LC with spectroscopic techniques are discussed. Advantages and limitations of various off-line and on-line approaches to method hyphenation are highlighted. Examples from recent literature with special focus on segmented copolymers (e.g. block, graft, miktoarm, multibranched or star copolymers) will be reviewed.
Keywords
LCCCTHFATRPPHBVDLSMMDELSDMALLSPolyisoprene2D-LCMultiangle Laser Light ScatteringPPOTGICPBOPoly(2-ethylhexyl acrylate)QELSP2VPmatrix-assisted laser desorption/ionization time-of-flight mass spectroscopygradient polymer elution chromatographyQuasi Elastic Light ScatteringLALLSPDMSSBSSECPCLLACESInuclear magnetic resonancePMAEvaporative Light Scattering DetectorUltravioletAtom transfer radical polymerizationPolypropylene oxidePolyethylene oxideFourier transform infraredTetrahydrofuranNMRMolar mass distributionHyphenated techniquesStructure–property relationshipsRefractive indexFTIRNormal phasereversed phasephoMALDI-TOF-MSViscHILICViscometryDynamic Light ScatteringCRPPoly(2-vinylpyridine)Poly(n-butyl methacrylate)PMMApolyethylene glycolpolymethyl methacrylatePolycaprolactoneControlled radical polymerizationPEGPolystyrenePolydimethylsiloxanePEOSize exclusion chromatographyInteraction chromatographyTemperature gradient interaction chromatographyliquid chromatographyhigh performance liquid chromatographyLiquid chromatography at critical conditionsTwo-dimensional liquid chromatographyhydrophilic interaction liquid chromatographyHPLCMultidimensional chromatographyGas chromatographyCaPSegmented copolymerselectrospray ionization
Related Topics
Physical Sciences and Engineering
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Authors
Muhammad Imran Malik, Harald Pasch,