Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5208987 | Progress in Polymer Science | 2009 | 38 Pages |
Abstract
As one of the major techniques developed to achieve surface modification of polymeric materials, UV-induced surface graft polymerization has been widely applied as a simple, useful and versatile approach to improve the surface properties of polymers. This review surveys the recent advances in UV light induced surface graft polymerizations, predominantly focusing on: (1) various initiating methods, controlled/living grafting, self-initiated grafting (grafting without the addition of photoinitiators), graft polymerizations with monomer pairs able to form charge transfer (CT) complexes, grafting in liquid, vapor and bulk phase, and the substrates used for grafting; (2) the topography of grafted surface layers, including granular structure, crosslinked structure, and well-defined structure; and (3) the application of techniques to prepare functionalized polymer surfaces with designed performances, e.g., to obtain polymer materials suitable for biomedical applications, membranes or microfluidics.
Keywords
AFMDMF2-hydroxyethyl acrylateFE-SEMCPPPDMSCOPHDPEFeCl3MPCMIPDVBPolypyrroleTHFPDAPPyPESPAAPLASAMSfMBTCISCPHBVVACLDPEATR-IRAQSCOCITxGMAePTFEAgNO3MBAAMAH2-hydroxyethyl methacrylateNVPAIBNPNIPAAmEPDMAEMA1,4-phenylenediamineBPOTHOPMAABOPPK2S2O8Conversion percentagen-Vinyl pyrrolidonepower of hydrogen2-Methacryloyloxyethyl phosphorylcholinePANIN,N-dimethylformamideUV–VisXanthoneanthraquinoneGlucose oxidaseUltravioletOzoneAcrylicOxygenbenzoyl peroxideBenzophenonetheophyllineFourier transform infraredModificationGODCarbon dioxideGrafting efficiencyHEAPolymer surfaceFT-IRIntersystem crossingMaleic anhydridePANSEMMolecular Imprinted PolymerCANField-emission Scanning Electron MicroscopyScanning electron microscopyOptical microscopyatomic force microscopyScanning force microscopyUV lightCeric Ammonium Nitratesilver nitrateXanHEMAVinyl acetatePETPolyacrylonitrilePoly(3-hydroxybutyrate-co-3-hydroxyvalerate)Poly(l-lactide)Poly(N-isopropylacrylamide)poly(dimethylsiloxane)Poly(methacrylic acid)Poly(methyl methacrylate)PMMAPolyanilinePoly(ether sulfone)PolyethylenePoly(ethylene terephthalate)High density polyethyleneLow density polyethylenePoly(ethylene glycol)PolypropyleneBiaxially oriented polypropyleneExpanded poly(tetrafluoroethylene)Graft polymerizationPolyacrylic AcidPEGPolystyreneGraftCadmium sulfideCdSFunctionalizationCO2ferric chlorideGlycidyl methacrylate
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Jianping Deng, Lifu Wang, Lianying Liu, Wantai Yang,