Article ID Journal Published Year Pages File Type
5209308 Reactive and Functional Polymers 2017 7 Pages PDF
Abstract

In this study, using a sequential polyamic acid (PAA) gelation and solvothermal imidization, we demonstrate a scalable one-pot solvothermal approach for the preparation of polyimide (PI) aerogels having a three-dimensional network composed of uniform microspheres. PI aerogels prepared by this approach were mechanically robust can be directly dried in oven without considerable contraction. More importantly, the PI aerogels showed morphology-enhanced water droplet contact angles from 98° to as high as 146°, which makes them nearly superhydrophobic. Such hydrophobic/oleophilic monolithic aerogels could rapidly and continuously separate oil from oil/water mixtures and even from water-in-oil emulsions.

Graphical abstractIn this study, we demonstrate a scalable one-pot solvothermal approach for the preparation of mechanically robust polyimide (PI) aerogels that can be directly dried in oven without considerable contraction. More importantly, PI aerogels prepared by this approach showed morphology-enhanced contact angles from 98° to as high as 146°; therefore, these aerogels could be used in novel pumping strategy for a continuous and rapid separation of oil from oil/water mixtures and emulsions.Download high-res image (137KB)Download full-size image

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Physical Sciences and Engineering Chemistry Organic Chemistry
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