Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5209327 | Reactive and Functional Polymers | 2017 | 9 Pages |
Abstract
The preparation of quaternary ammonium salts containing allyl and methallyl groups from dimethylamine and pyrrolidine, and the free-radical initiated cyclopolymerization of these salts is described. It is shown by NMR analysis that poly(ammonium salts) are formed consisting of pyrrolidinium and azoniaspiro[4.4]nonane containing repeating units respectively with one or even two adjacent quaternary carbon centers along the chain. The ability to polymerize decreased from diallyl over allylmethallyl to dimethallyl monomers. Already polymers from diallylammonium salts showed sufficient stability in alkaline medium at 80 °C over a period of 168 h and for additional 18 h at 120 °C.
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Claus Vogel, Hartmut Komber, Jochen Meier-Haack,