Article ID Journal Published Year Pages File Type
5209483 Reactive and Functional Polymers 2016 9 Pages PDF
Abstract
A new triphenylamine-based diamine monomer 4,4′-diamino-4″-(1-piperidinyl)triphenylamine was synthesized and polymerized with various aromatic dicarboxylic acids via the phosphorylation polyamidation technique leading to a series of redox-active aromatic polyamides (aramids). All the aramids exhibit good solubility in many organic solvents and can be solution-cast into flexible and strong films with high thermal stability. Cyclic voltammograms of the polymer films on the indium-tin oxide (ITO)-coated glass substrate exhibit a pair of well-defined and reversible oxidation waves with very low onset potentials of 0.27-0.35 V (vs. Ag/AgCl) in acetonitrile solution, with a strong color change from colorless neutral form to green and deep blue oxidized forms in the range of 0.75-1.20 V. The optical transmittance change (Δ%T) at 636 nm between the neutral state and the fully oxidized state is up to 83%.
Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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