Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5209573 | Reactive and Functional Polymers | 2016 | 22 Pages |
Abstract
Lignosulfonate-g-acrylic acid (LS-g-AA) hydrogels that possess superabsorbent capacity were synthesized by grafting acrylic acid (AA) on the backbone of lignosulfonate (LS) in the presence of N,Nâ²-methylene-bis-acrylamide (MBA) as initiated by laccase/t-BHP(tert-butyl hydroperoxide). Specifically, the carboxylic acid groups introduced by grafting acrylic acid, significantly enhanced the absorption capacity of LS-g-AA hydrogels. In this case, methylene blue (MB) was the representative dye substrate to study absorption dynamics. It was found that the equilibrium absorption of MB reached 2013 mg·gâ 1 while pH, absorption time, and initial MB concentration affected the overall absorption capacity. The absorption isotherms and kinetics obeyed standard Freundlich and pseudo-2nd-order models, respectively. Furthermore, preliminary desorption experiments were conducted in weak acid solution and showed that ~ 50% of the original MB could be removed over one rinse cycle.
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Authors
Chenghua Yu, Feng Wang, Chunhui Zhang, Shiyu Fu, Lucian A. Lucia,