Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5209845 | Reactive and Functional Polymers | 2014 | 6 Pages |
Abstract
In this paper, a novel thiophene based monomer, 1-(pyren-1-yl)-2,5-di(thiophen-2-yl)-1H-pyrrole, PThP, was synthesized and characterized by 1H NMR and 13C NMR spectroscopic methods. The electrochemical behavior and electropolymerization of this novel monomer were performed on pencil graphite electrode (PGE) by cyclic voltammetry. The effect of solvent, dopant, scan number and scan rate on the electropolymerization and properties of the conjugated polymer films were investigated. The capacitive properties of the poly(PThP) films were tested by electrochemical impedance spectroscopy (EIS). The highest specific capacitance value was calculated for the conjugated polymer modified PGE that was obtained in 0.1Â M tetrabutylammonium perchlorate/dichloromethane solution for 30 cycles at 25Â mV/s scan rate as 25.45Â mFÂ cmâ2. The surface morphologies of the conjugated polymer modified electrodes were determined by scanning electron microscopy (SEM).
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Burcu Ãelik, Ä°lhami Ãelik, Hacer DolaÅ, Hakan Görçay, Yücel Åahin, A. Sezai Saraç, Kadir Pekmez,