Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5209858 | Reactive and Functional Polymers | 2014 | 12 Pages |
Abstract
Macrocyclic oligomers (MCOs) are important as starting materials for Entropically-driven Ring-opening Polymerizations (ED-ROPs). This article reviews the preparation of MCOs by the cyclodepolymerization (CDP) of condensation polymers. Many MCOs have been prepared successfully this way and in numerous cases individual macrocycles have been isolated. This approach can provide one-step syntheses of many macrocycles. The combination of CDP plus ED-ROP is an attractive potential method for recycling ('Ring-chain Recycling') many condensation polymers.
Related Topics
Physical Sciences and Engineering
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Authors
Philip Hodge,