Article ID Journal Published Year Pages File Type
5209858 Reactive and Functional Polymers 2014 12 Pages PDF
Abstract
Macrocyclic oligomers (MCOs) are important as starting materials for Entropically-driven Ring-opening Polymerizations (ED-ROPs). This article reviews the preparation of MCOs by the cyclodepolymerization (CDP) of condensation polymers. Many MCOs have been prepared successfully this way and in numerous cases individual macrocycles have been isolated. This approach can provide one-step syntheses of many macrocycles. The combination of CDP plus ED-ROP is an attractive potential method for recycling ('Ring-chain Recycling') many condensation polymers.
Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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