Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5210051 | Reactive and Functional Polymers | 2013 | 7 Pages |
Abstract
The synthesis of isocyanate free polyurethanes is a major concern. This paper first reports the synthesis of new biobased isosorbide dicyclocarbonates from isosorbide. Then polyhydroxyurethanes (PHUs) were synthesized by a cyclocarbonate-amine step growth polyaddition with four commercial diamines (e.g. jeffamine D-400, 1,10 diaminodecane, diethylenetriamine and isophoronediamine). These unprecedented products, obtained with high yield, were characterized by 1H NMR, FTIR, DSC, SEC and TGA analyses. PHUs exhibited glass transition temperatures from â8 °C to 59 °C, and degradation temperatures (Td 5%) between 234 °C and 255 °C. Last but not least, the compounds produced during the degradation of these PHUs were analyzed by ATG-IR technique and showed that carbon dioxide and secondary amines are released.
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Authors
Vincent Besse, Rémi Auvergne, Stéphane Carlotti, Gilles Boutevin, Belkacem Otazaghine, Sylvain Caillol, Jean-Pierre Pascault, Bernard Boutevin,