Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5210215 | Reactive and Functional Polymers | 2011 | 7 Pages |
Abstract
Two kinds of monomers containing the thioether units 4,4â²-thiodibenzoyl chloride (T-DC) and 4,4â²-bis(4-chloroformylphenylthio)benzene (BPB-DC) were synthesized in two steps and were reacted with diamine-containing thioether (-S-) and sulfone units to prepare a polyamide containing high contents of thioether groups. The intrinsic viscosities of the polyamides were 0.81-0.93 dl/g. These polymers had good optical properties, including an optical transmittance of the aromatic polyamide film at 450 nm that was higher than 90%. Additionally, the high quantity of thioether units provided the polymers with high refractive indices of 1.710-1.716 and low birefringences of 0.007-0.009. These polyamides also had excellent thermal properties, with glass transition temperatures (Tg) of 230-246 °C and initial degradation temperatures (Td) of 477-473 °C. Finally, they showed improved solubility in polar aprotic solvents.
Related Topics
Physical Sciences and Engineering
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Authors
Gang Zhang, Dong-sheng Li, Guang-shun Huang, Xiao-jun Wang, Sheng-ru Long, Jie Yang,