Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5210716 | Reactive and Functional Polymers | 2010 | 7 Pages |
Abstract
Well-defined photo-responsive alternating copolymers, poly(4-(N-maleimido)azobenzene-alt-styrene)s (PMSts), were successfully synthesized via reversible addition-fragmentation chain transfer (RAFT) polymerization. A divinyl monomer was used in this polymerization to prepare high molecular weight azobenzene polymers. These polymers had good solubility in most organic solvents, formed films well, and had high glass transition temperatures (Tg = 174-250 °C) and were heat resistant (Td > 320 °C). The photo-induced trans-cis isomerization of the copolymers was examined in chloroform solution. Surface-relief-gratings (SRGs) formed on the polymer films were also investigated using illumination from a linearly polarized Kr+ laser beam.
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Xiaoqiang Xue, Jian Zhu, Zhengbiao Zhang, Nianchen Zhou, Xiulin Zhu,