Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5210931 | Reactive and Functional Polymers | 2007 | 11 Pages |
Abstract
This paper reports a novel nonlinear optical polymer BP-AVT-TCV functionalized with a thiophene- and tricyanovinyl-substituted chromophore. BP-AVT-TCV was synthesized by the post-tricyanovinylation of an epoxy-based precursor polymer BP-AVT, and had a high molar functionalization degree of chromophore (70 mol.%). It had an enhanced glass transition temperature (Tg = 164 °C) compared with BP-AVT (Tg = 114 °C), and a high decomposition temperature (Td,5% = 295 °C). BP-AVT-TCV was further cross-linked to achieve the three-dimensional (3D) network of thermosetting polyurethane (PU). The poled PU films revealed an electro-optic (EO) coefficient (γ33) value of 21 pm/V at a wavelength of 1315 nm. The structures of the polymers were confirmed by FT-IR, UV-Vis, and 1H NMR spectra.
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Authors
Jumin Hao, Mei-Juan Han, Kunpeng Guo, Jianfeng Zhai, Tao Zhang, Xiaoguang Meng, Junfeng Liang, Ling Qiu, Yuquan Shen,