Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5211514 | Reactive and Functional Polymers | 2006 | 9 Pages |
Abstract
Plasma polymerized acrylic acid (PPAA) coatings were deposited on PE films, in a 70Â kHz low pressure plasma reactor, at various plasma powers. The COOH retention of PPAA coatings and its stability to washing in water were investigated by XPS, WCA (water contact angle), FTIR, ellipsometry and SEM analyses. The results have shown that the use of higher powers leads to an increase of the stability of the coating due to a high degree of cross-linking. Under optimized conditions, it is possible to obtain stable PPAA coatings which resist to washing with a COOH retention rate of 15% on PE, which is much higher than the coating deposited in a 13.56Â MHz discharge. This high stability of the coatings observed in the low frequency discharge, which is somewhat similar to DC glow discharges, is probably due to the ions which play an important role in the cross linking process of the coatings. Optical emission spectroscopy measurements (OES) have shown good correlation between the CO density in the gas phase and the carboxylic content of PPAA coating.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
R. Jafari, M. Tatoulian, W. Morscheidt, F. Arefi-Khonsari,