Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5211723 | Reactive and Functional Polymers | 2006 | 8 Pages |
Abstract
Polyurethane foam functionalized with α-naphthol was synthesis by covalently linking them through an NN group. The characterization of 1-naphthol bonded to polyurethane foam (1-Nap-PUF) and the sorption behaviour of Ni2+ and Cu2+ on 1-Nap-PUF have been investigated. The optimum pH ranges for quantitative sorption were 6-10. The kinetics of sorption of the metal ions by the 1-Nap-PUF were found to be fast, reaching equilibrium in few minutes (5-10 min) and followed a first-order rate equation with an overall rate constant k in the range 0.16-0.22 minâ1. The numerical values of thermodynamics parameters enthalpy (ÎH), entropy (ÎS) and Gibbs free energy (ÎG) indicated the exothermic and spontaneous nature of sorption. The sorption data followed Freundlich and Dubinin-Radushkevich (D-R) type sorption isotherms. The average value of the sorption free energy ÎE = 9.84 kJ molâ1 indicating ion exchange or chelations type chemisorption. The capacities of 1-Nap-PUF were 0.22 and 0.2 mmol gâ1 for Ni2+ and Cu2+, respectively. The 1-Nap-PUF was used to determine these metal ions in iron, granite. On the basis of these parameters, the sorption mechanism was discussed.
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Authors
E.A. Moawed, M.F. El-Shahat,