Article ID Journal Published Year Pages File Type
52119 Catalysis Communications 2008 9 Pages PDF
Abstract

A convenient and green method for the synthesis of aromatic 2-oxazolines, 2-imidazolines and 2-thiazolines using tungstophosphoric acid (TPA), a commercially available, stable and reusable catalyst, from the reaction of aromatic nitriles and 2-aminoalcohols, ethylenediamine or 2-aminoethanethiol under solvent-free conditions is reported. It is noteworthy that this procedure could be used for selective synthesis of mono- and bis-oxazolines and imidazolines from dicyanobenzene. In three cases the catalyst could be reused several times without significant loss of its catalytic activity.

Related Topics
Physical Sciences and Engineering Chemical Engineering Catalysis
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