Article ID Journal Published Year Pages File Type
5212126 Tetrahedron 2017 5 Pages PDF
Abstract

Novel disulfuration was established via cross coupling between nucleophilic disulfurating reagent and arylsilane introducing two sulfur atoms in one step. This methodology was applied to synthesize various unsymmetrical disulfides under mild conditions via copper-catalyzed oxidative Hiyama-type cross coupling, providing a new pathway for disulfide synthesis. In addition, pH value of system displayed a key role in alcoholysis process.

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Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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