Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5212126 | Tetrahedron | 2017 | 5 Pages |
Abstract
Novel disulfuration was established via cross coupling between nucleophilic disulfurating reagent and arylsilane introducing two sulfur atoms in one step. This methodology was applied to synthesize various unsymmetrical disulfides under mild conditions via copper-catalyzed oxidative Hiyama-type cross coupling, providing a new pathway for disulfide synthesis. In addition, pH value of system displayed a key role in alcoholysis process.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Zhihong Dai, Xiao Xiao, Xuefeng Jiang,