| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5212366 | Tetrahedron | 2017 | 7 Pages |
Abstract
The palladium(II)-catalyzed direct oxidative C–H olefination of readily available N-tosylacrylamides and allenoates for the synthesis of dienyl esters is described. The amide and ester moieties both act as the directing groups for the regio- and the stereo-controlled C–H functionalization/cyclization, which was proved by DFT calculations. Molecular oxygen was used as the terminal oxidant in the approach, rendering the reaction more sustainable.
Graphical abstractFigure optionsDownload full-size imageDownload high-quality image (165 K)Download as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
