Article ID Journal Published Year Pages File Type
5213798 Tetrahedron 2016 4 Pages PDF
Abstract

An anthracene-based gelator (AHP-mB8) has been designed and synthesized. AHP-mB8 can form thermo-reversible gels in some of the tested solvents. FTIR, temperature-dependent 1H NMR, UV-vis and XRD spectra indicated that the gelator self-assembles into a fibrous network possibly due to the combination of intermolecular hydrogen bonding and π-π interactions. The anion binding studies indicated that AHP-mB8 has remarkable and specific F− selectivity over other tested anions to exhibit yellow-red color changes for easy naked-eye detection. The Enhanced Fluorescence Emission has been observed after gelation although the dilute solution of AHP-mB8 was almost non-fluorescent.

Graphical abstractDownload full-size imageThe organogel of an anthracene derivative exhibited gelation-induced enhanced fluorescence emission, and it was selectively fluoride-responsive among test anions, expressing gel-sol transition and yellow-red color changes for easily naked-eye detection.

Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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