| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5214100 | Tetrahedron | 2016 | 6 Pages |
Abstract
New phosphine-sulfide and phosphine-sulfoxide ligands were synthesized and tested in allylic alkylation. Their coordination mode with Palladium have been studied by analysis of the corresponding X-ray crystallographic structures. The most efficient ligands were prepared in enantiomerically pure form and were applied to the Pd-catalyzed asymmetric allylic alkylation providing enantioselectivities up to 74%.
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