| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5214125 | Tetrahedron | 2015 | 5 Pages |
Abstract
While Pd-catalyzed allyl-allyl cross-couplings in the presence of small-bite-angle bidentate ligands reliably furnish the branched regioisomer with high levels of selectivity, cross-couplings in the presence of large-bite-angle bidentate ligands give varying, often unpredictable, levels of selectivity. In a combined computational and experimental study, we probe the underlying features that govern the regioselectivity in these metal-catalyzed cross-couplings.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Michael J. Ardolino, James P. Morken,