| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5214130 | Tetrahedron | 2015 | 10 Pages |
Abstract
A palladium complex derived from Pd2(dba)3 and tris(2,4,6-trimethoxyphenyl)phosphine catalyzes the addition reaction of thioesters to norbornenes, giving trans-2-acyl -3-organothionorbornanes. The trans-adducts are predominantly obtained with the acyl group at the endo-position and the organothio group at the exo-position. Aroyl and heteroaroyl thioesters as well as alkanoyl thioesters were reacted, including S-(4-tolyl) phenylthioglyoxylate and methyl 2-(4-tolylthio)-2-oxo-acetate.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Mieko Arisawa, Saori Tanii, Tomoki Yamada, Masahiko Yamaguchi,