| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5214267 | Tetrahedron | 2015 | 5 Pages |
Abstract
Methods for generating tert-alkyl organoboron species are in high demand as they are invaluable intermediates for the synthesis of quaternary carbon centres. Herein we report investigations into generation of tert-alkyl organoboron species using imidoyl chlorides as reagents in the organoboron cyanidation reaction. Although alkenyl side-products predominate in particularly hindered cases, tert-alkyl organoboron species can be successfully generated for less hindered examples.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Dyfyr Heulyn Jones, Keith Smith, Mark C. Elliott, Gamal A. El-Hiti,