Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5214742 | Tetrahedron | 2015 | 7 Pages |
Abstract
An efficient 2,3-dichloro-5,6-dicyano-1,4-benzoquinone/tert-butyl nitrite-catalyzed aerobic oxidation of diarylmethane sp3 C-H bonds in the presence of acetic acid has been developed. Under the optimal reaction conditions, a number of diarylmethanes can be directly converted to their corresponding diarylketones in good to excellent yields. In addition, a plausible reaction mechanism has been investigated.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Jiaqi Ma, Zhiming Hu, Meichao Li, Weijuan Zhao, Xinquan Hu, Weimin Mo, Baoxiang Hu, Nan Sun, Zhenlu Shen,