| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5215033 | Tetrahedron | 2015 | 6 Pages |
Abstract
A new facile and efficient one-pot procedure for the synthesis of 3-phenyl-3-silatetrahydropyrans with an easily functionalized Si-Ph bond was developed. The method is based on the intramolecular cyclization of chloromethyl(3-hydroxypropyl)phenylsilanes using the n-Bu4NBr/i-Pr2NEt combination. As an example of functionalization, the synthesis of the first 3-silatetrahydropyran with an exocyclic RO-Si bond is reported.
Graphical abstractDownload full-size image
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Svetlana V. Kirpichenko, Bagrat A. Shainyan,