| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5215119 | Tetrahedron | 2015 | 4 Pages |
Abstract
A one-pot Rh(I)-catalyzed synthesis of 9-H carbazoles via C–N bond cleavage by activation of aldehyde C–H bonds is reported. This protocol offers good yields and tolerates a broad range of functional groups. Based on the extensive control experiments, we propose a plausible decarbonylation mechanism.
Graphical abstractA one-pot Rh(I)-catalyzed synthesis of 9-H carbazoles via C–N bond cleavage by activation of aldehyde C–H bonds is reported. This protocol offers good yields and tolerates a broad range of functional groups. Based on the extensive control experiments, we propose a plausible decarbonylation mechanism.Figure optionsDownload full-size imageDownload high-quality image (136 K)Download as PowerPoint slide
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