Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5215599 | Tetrahedron | 2015 | 7 Pages |
Abstract
A dual neutral-cationic rhodium(I)-catalyzed Pauson-Khand-type reaction using formaldehyde as a carbonyl source is described. The simultaneous use of neutral rhodium(I) and cationic rhodium(I) complexes is required for efficient cooperative catalysis, which involves the neutral rhodium(I)-catalyzed decarbonylation of formaldehyde and the cationic rhodium(I)-catalyzed cyclocarbonylation of 1,6-enynes using the resulting carbonyl moiety.
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Takuma Furusawa, Tsumoru Morimoto, Keiichi Ikeda, Hiroki Tanimoto, Yasuhiro Nishiyama, Kiyomi Kakiuchi, Nakcheol Jeong,