Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5215794 | Tetrahedron | 2014 | 5 Pages |
Abstract
An efficient method of Titanium(IV) mediated one-pot reaction approaching aromatic homoallylic alcohols from aldehydes and dual Grignard reagents was developed with good isolated yields. This method could use aromatic-, heteroaromatic-, or aliphatic-aldehydes as starting materials. However, electron-riched benzaldehyde or cinnamaldehyde tended to precede further hydroxyl eliminations to give all conjugated structures as demonstrated.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Xiao-Nan Song, Lei Lu, Si-Kai Hua, Wei-Dong Chen, Jiangmeng Ren,