| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5216106 | Tetrahedron | 2014 | 7 Pages |
Abstract
Transformation of cyclohexa-1,3- and 1,4-dienes to carbasugars is described. Photooxygenation of dienes gave bicyclic endoperoxides, which were reduced with thiourea to the corresponding 1,4-diols with cis-configuration. Lactonization of the remaining double bond by oxidative addition of acetic acid to the double bond in the presence of Mn(OAc)3 followed by lactone ring-opening reaction gave the target branched carbasugars.
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Yasemin Altun, Sengul Dilem Dogan, Metin Balci,