Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5216289 | Tetrahedron | 2014 | 6 Pages |
Abstract
Rigid tetrahedral compounds T1 and T2 that bear four tetrathiafulvalene (TTF) units, which are connected to a tetraphenylmethane core by the ethynylene or amide linker were designed and prepared. Upon one-electron oxidation of the TTF units by Fe(ClO4)3, the resulting TTF+ radical cations stacked intermolecularly to give rise to three-dimensional supramolecular polymers, which were supported by UV-vis spectroscopy, cyclic voltammetry, dynamic light scattering, and scanning electron microscopy.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Lan Chen, Shao-Chen Zhang, Hui Wang, Ya-Ming Zhou, Zhan-Ting Li, Dan-Wei Zhang,