| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5216680 | Tetrahedron | 2014 | 6 Pages |
Abstract
A series of enantioenriched six-membered metallocyclic amidomagnesium naphtholates were prepared and used to probe the structure-reactivity/selectivity relationships of heteroleptic magnesium base complexes within asymmetric deprotonation reactions. An effective complex was identified and applied within enantioselective enolisation processes, delivering good levels of enantioselectivity and also revealing key structural requirements for achieving such selectivity.
Graphical abstractDownload full-size image
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Emma L. Carswell, William J. Kerr, Duncan McArthur, Marek Pažický, Allan J.B. Watson,