Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5216749 | Tetrahedron | 2013 | 4 Pages |
Abstract
The aminopalladation of amino allylic alcohol using Cl2Pd(MeCN)2 in CH2Cl2 gave the 2,6-disubstituted piperidine with excellent diastereoselectivity. This compound was successfully converted into (+)-azimine (1) using cross-metathesis and Shiina macrolactonization.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Yuji Kurogome, Masaya Kogiso, Kok Kong Looi, Yasunao Hattori, Hiroyuki Konno, Mitsuru Hirota, Hidefumi Makabe,