| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5217227 | Tetrahedron | 2013 | 7 Pages |
Abstract
The reactivity of electron-deficient arene–gold(III) complexes toward nucleophilic aromatic and heteroaromatic counterparts has been studied. 1-Methylindole proved to be the best reaction partner while trimethoxybenzenes did not react. The ancillary ligand on gold also influenced the reactivity in the order PPh3>PtBu3>IPr. An oxidative cross-coupling starting from the corresponding gold(I) complexes in presence of hypervalent iodide oxidants was also studied.
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