Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5217243 | Tetrahedron | 2014 | 5 Pages |
Abstract
The stereochemistry of inuloidin (1), which was a sesquiterpenoid that was characterized as a plant growth inhibitory substance from Heterotheca inuloides, was investigated. The modified Mosher's method coupled with a total synthetic study using osmium oxidation and Burgess dehydration as key steps were performed to clarify the stereochemistry of 1, which was determined to be a 2S,4R isomer.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Jumpei Kamatani, Takehiro Iwadate, Reiko Tajima, Hideaki Kimoto, Yoichi Yamada, Noriyoshi Masuoka, Isao Kubo, Ken-ichi Nihei,